OK… I’ll bite!
I’ve been using SolidWorks since its 1995 beta and pre-release… with some breaks in between on other jobs.
I was trained in Inventor and used it back around 2011… In the year and a half I started using Inventor again (2021), I would have thought that it would have progressed much further since … It was woeful in 2011 and before that, and it’s pretty horrible now, IMO
This subject is pretty dear to me, mostly because I hear the ‘What’s better?’ question so often… and the answer is “They’re similar” or “They’re basically the same” or “You can do the same job in both”… and these answers are true, actually, but at the same time not when it comes to the nitty gritty of getting the job done… or heaven forbid, if you need to make changes!
Inventor is not so user friendly to me (unless maybe if you’re used to AutoCAD methodologies) and arguably the worst 3d CAD software I’ve used in the 30+ years I’ve been involved with 3D CAD systems, especially when it comes to the UI… Inventor somewhat reminds me of the old ProEngineer style of input where you’d need to navigate down through the command menu structure, and then navigate back out… done done done done ad-nauseum
Don’t get me wrong… There are a few things I preferred in Inventor; the graphics seemed better, the stability in complex and large assemblies was a bit better, I thought the Inventor Hole Feature was prettier than SolidWorks’ (until I had to terminate a hole offset from a face or other feature start/end termination).
I think it really started falling apart when ADSK decided to write their own constraint and modelling kernels, and also when they decided to not worry about UI consistancy, with short cut and menu items changing places here and there.
The ‘adaptivity’ feature, the whole ethos of parametric CAD systems is so rife with errors to the point of needing to turn adaptivity off (which was recommeded by all the expert users also)… Don’t expect mirrored entities in sketches to stay constrained as symmetric for long… oy vay!
It’s hard to believe such a wannabe CAD system is from a company as large and with the resources that Autodesk has… I say a wannabe CAD system because it seems it’s whole reason for being is driven by trying to keep up with SolidWorks instead of any hint of real innovation… it’s feature set development seems to mimmick SolidWorks closely enough to predict its feature release schedule pretty closely… SolidWorks releases a feature, ADSK tries to cobble something together so sales can tick the box… Have a look at model states! Maybe they’ve made it better by now, but it was an absolute sht show just a few years ago and so far away from configurations and display states in usability that it was almost unusable. Presentation mode for exploded assemblies? WTF!!!
The amount of mouse clicks and rework due to the plethora of bugs and instability throughout the system just utterly amazes me to the point of wondering how companies can justify the cost in lost time compared to systems costing much more.
To me, Inventor is the perfect example of poor planning and lack of experience all piled on an extremely weak foundation.
Inventor may be able to acheive a similar result as SolidWorks with a lot of work or basic bottom-up style modelling, but its lack of flexibility, poor UI, unproductive model and assembly feature sets, and poor drawing creation capabilities prove this not to be the case, especially when comparing time spent on similar tasks across the board.
If you got this far, thanks for reading, and allowing me to have this rant… it’s a load off, but please correct me if I’m wrong! 
PS:
Dear Autodesk, you need to do (much) better… your product is sub-standard and counter-productive… Lift your game!